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1 article(s) from Vella, Sarah J

A pyridinium/anilinium [2]catenane that operates as an acid–base driven optical switch

Sarah J. Vella and
Stephen J. Loeb

Beilstein J. Org. Chem. 2018, 14, 1908–1916, doi:10.3762/bjoc.14.165

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Graphical Abstract

Figure 1: Two [2]rotaxane molecular shuttles with both bis(pyridinium)ethane and benzylanilinium recognition ...

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Figure 2: A [3]catenane containing two identical bis(pyridinium)ethane recognition sites on a large macrocycl...

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Scheme 1: Step-wise synthesis of [2]catenane [8 [Graphic 3] DB24C8]⁶⁺ containing benzylanilinium and bis(pyridinium)ethane...

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Figure 3: ¹H NMR spectrum of [2]catenane [8 [Graphic 3] DB24C8]⁶⁺ (500 MHz, 298 K, CD₂Cl₂) showing the assigned proton che...

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Figure 4: a) The [2]catenane [8 [Graphic 3] DB24C8]⁶⁺ can be protonated to yield [8-HDB24C8]⁷⁺ in two different co-conform...

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Figure 5: UV–visible spectra of [8 [Graphic 3] DB24C8]⁶⁺ (orange trace) and [8-HDB24C8]⁷⁺ (black trace) in CH₃CN solution ...

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Published 25 Jul 2018

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